1-(2-Methylbenzoyl)-3-m-tolylthiourea
نویسندگان
چکیده
The molecule of the title compound, C(16)H(16)N(2)OS, is not planar; the two aromatic rings are inclined to one another by 37.59 (9)°. There are intra-molecular hydrogen bonds between the benzoyl O atom and the H atom of the thio-amide N atom, and between the thio-urea S atom and the H atom of the tolyl group. These hydrogen bonds stabilize the mol-ecule in such a way that the thio-urea group adopts a trans-cis geometry. In the crystal structure, mol-ecules are linked by N-H⋯S inter-molecular hydrogen bonds, forming centrosymmetric dimers.
منابع مشابه
1-(4-Methylbenzoyl)-3-{2-[3-(4-methylbenzoyl)thioureido]phenyl}thiourea
In the title compound, C(24)H(22)N(4)O(2)S(2), the dihedral angles formed by the thio-ureido groups with the attached benzene ring are 43.81 (13) and 75.25 (13)°. The dihedral angle between the thio-ureido groups is 85.48 (10)°. The mol-ecule is stabilized by intra-molecular N-H⋯S, N-H⋯O and C-H⋯S hydrogen bonds. In the crystal, molecules are linked by intermolecular N-H⋯S hydrogen bonds togeth...
متن کامل2-Methyl-N-(3-methylbenzoyl)benzenesulfonamide
In the title compound, C(15)H(15)NO(3)S, the sulfonyl and amide-bound benzene rings are oriented at dihedral angles of 83.1 (1) and 22.5 (3)°, respectively, with the almost planar S-N-C=O segment (r.m.s. deviation = 0.003 Å). The dihedral angle between the two benzene rings is 74.8 (1)°. In the crystal structure, pairs of mol-ecules are linked into centrosymmetric dimers by pairs of N-H⋯O hydro...
متن کامل2-Methyl-N-(2-methylbenzoyl)benzenesulfonamide
In the title compound, C(15)H(15)NO(3)S, the 2-methyl-phenyl ring bonded to the sulfonyl group is disordered with site-occupation factors of 0.75:0.25. The dihedral angles between the two aromatic rings are 67.6 (1) and 69.2 (1)° for the major and the minor occupied sites, respectively. In the crystal, mol-ecules are linked into centrosymmetric dimers by pairs of N-H⋯O hydrogen bonds.
متن کامل2-Chloro-N-(3-methylbenzoyl)benzenesulfonamide
In the title compound, C(14)H(12)ClNO(3)S, the N-H bond is in an anti-periplanar conformation to the C=O bond. The dihedral angle between the two aromatic rings is 74.7 (1)°. The crystal structure features inversion-related dimers linked by N-H⋯O hydrogen bonds.
متن کامل2-Chloro-N-(2-methylbenzoyl)benzenesulfonamide
In the title compound, C(14)H(12)ClNO(3)S, the N-H bond is anti-periplanar to the C=O bond. The dihedral angle between the two aromatic rings is 78.7 (1)°. The crystal structure features inversion-related dimers linked by pairs of N-H⋯O(S) hydrogen bonds.
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عنوان ژورنال:
دوره 64 شماره
صفحات -
تاریخ انتشار 2008